The water resources in Hebei Province are short and seriously polluted in the process of urbanization, leading to constraints on the urbanization development and water resource system. Based on the reasonable establishment of the evaluation index system, the coupling coordination between the urbanization and water resource system in Hebei Province is empirically analyzed by using AHP to give weights and combining with the coupling coordination degree model. The results show that the urbanization level of Hebei Province monotonically increases and rapidly develops during the period of 2005 to 2014, while the development of the water resource system is relatively slow, and there is a significant turning point in 2012. The coupling coordination degree of the two systems first increases and then decreases. By using the exponential smoothing method to predict the coupling coordination degree of the next 3 years, the conclusion is drawn that the coupling coordination will continue to decrease, and reasonable suggestions are also put forward.