渗流盐侵耦合作用下水泥砂浆力学性能酸蚀劣化规律
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(1.河海大学水利水电学院;2.南京现代综合交通实验室;3.中交水运规划设计院有限公司;4.宁波市水利水电规划设计研究院有限公司;5.西安市市政建设(集团)有限公司)

作者简介:

张延贺(2001—),男,硕士研究生,主要从事水泥基材料溶蚀研究。E-mail:zyh6565zyh@163.com

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国家自然科学基金面上项目(521035511);综合交通运输理论交通运输行业重点实验室(南京现代综合交通实验室)开放课题项目(MTF2023010)


Acid corrosion-induced deterioration law of mechanical properties of cement mortar under coupled seepage and salt attack
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(1.Collegeof Water Conservancy & Hydropower Engineering, Hohai University;2.NanjingModern Multimodal Transportation Laboratory;3.WaterTransportation Consultants Co., Ltd.;4.NingboWater Conservancy & Hydropower Planning and Design Institute Co., Ltd.;5.Xi’an Municipal Construction (Group) Co., Ltd. )

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    摘要:

    为探究渗流-盐侵耦合作用下水泥砂浆力学性能酸蚀劣化规律,开展了不同酸性环境(pH=7、3、1)Na2SO4溶液及渗流作用下水泥砂浆侵蚀试验、单轴压缩试验和劈裂抗拉试验,揭示了渗流-盐侵耦合作用下水泥砂浆在不同酸度条件中的力学性能劣化机理,建立了水泥砂浆力学性能劣化分析模型。结果表明:pH为7和3时水泥砂浆试样抗压强度和抗拉强度随侵蚀历时先增大后减小,侵蚀历时为60、45.d时,达到最大值,分别为39.33、3.12 mPa和36.71、2.86 mPa;pH为1时,水泥砂浆试样抗压强度和抗拉强度减小,其最大值分别为31.00和2.30 mPa;侵蚀溶液酸度越大,水泥砂浆抗压强度与抗拉强度最大值越小,力学性能劣化效应越显著;渗流-盐侵耦合作用下,随酸度增大,水泥砂浆由主要发生溶出性侵蚀和硫酸盐侵蚀耦合作用转为酸性侵蚀为主导;渗流-盐侵耦合作用下水泥砂浆强度损伤系数与侵蚀历时呈现良好的二次函数关系,且抗拉强度与抗压强度之间具有线性相关性。

    Abstract:

    To investigate the acid corrosion-induced deterioration law of mechanical properties of cement mortar under coupled seepage and salt attack, cement mortar erosion tests, uniaxial compression tests, and splitting tensile tests were carried out under different acidic conditions (pH=7, 3, and 1) in Na2SO4 solution with seepage. The deterioration mechanism of the mechanical properties of cement mortar under the coupled seepage and salt attack under different acidity conditions was revealed, and a deterioration analysis model for the mechanical properties of cement mortar was established. The results show that at pH of 7 and 3, the compressive strength and tensile strength of cement mortar specimens initially increase and then decrease with increasing erosion duration, reaching their peak values at 60 d and 45 d, respectively. Specifically, the peak compressive strength and tensile strengths are 39.33 MPa and 3.12 MPa at pH of 7, as well as 36.71 MPa and 2.86 MPa at pH of 3. In contrast, at a pH of 1, the compressive strength and tensile strength of the cement mortar specimens decrease, with their maximum values being 31.00 MPa and 2.30 MPa, respectively. A higher acidity of the erosion solution indicates a lower peak compressive strength and tensile strength of cement mortar and a more pronounced deterioration effect of mechanical properties. Under coupled seepage and salt attack, as acidity increases, the deterioration of cement mortar shifts from being dominated by the coupled action of leaching erosion and sulfate attack to being dominated by acid erosion. Under the coupled seepage and salt attack, the strength damage coefficient of cement mortar exhibits a good quadratic function relationship with erosion duration, and there is a linear correlation between tensile strength and compressive strength.

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张延贺,徐力群,赵邵峰,等.渗流盐侵耦合作用下水泥砂浆力学性能酸蚀劣化规律[J].河海大学学报(自然科学版),2026,54(3):92-100.(Zhang Yanhe, Xu Liqun, Zhao Shaofeng, et al. Acid corrosion-induced deterioration law of mechanical properties of cement mortar under coupled seepage and salt attack[J]. Journal of Hohai University (Natural Sciences),2026,54(3):92-100.(in Chinese))

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  • 收稿日期:2024-11-18
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  • 在线发布日期: 2026-05-28
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