This study reviewed the environmental behavior of microplastics(including the adsorption of organic pollutants and the release of organic additives after entering water), and the interaction between microplastics and organic pollutants after entering into water body, including its mechanism, influencing factors and biological toxicity. It also analyzed the deficiencies of current researches, and believed that, in order to provide theoretical basis for further study on the behavior and function of microplastics, it is necessary to expand the research on the interaction between microplastics and organic pollutants, such as strengthening the research in the freshwater environment, establishing systematic research system, and paying attention to the effect of biofilm