Fe掺杂A-TiO2在溴甲酚绿中的可见光催化活性及动力学
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

X703.1

基金项目:

教育部第四批高等学校特色专业建设点资助项目(TS11524);江西省精品课程资助项目(赣教高字〔2011〕74号);江西省精品资源共享课资助项目(赣教高字〔2015〕79号)


Visible light catalytic activity and kinetics of Fe-doped A-TiO2 in bromocresol green
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 文章评论
    摘要:

    以FeCl3·6H2O为Fe源,采用水热法制备了Fe掺杂锐钛型TiO2(A-TiO2)光催化剂。以溴甲酚绿为降解对象,考察溴甲酚绿的初始浓度、催化剂用量、掺Fe量等因素对自制催化剂可见光催化降解反应的动力学方程的影响。结果表明:在40 W白炽灯照射下,当溴甲酚绿初始浓度为10 mg/L(pH=7)、催化剂的用量为0.6 g/L、掺Fe量为4%(摩尔分数)、室温下反应时间为3 h时,溴甲酚绿的降解率最大为76.05%。溴甲酚绿光催化降解曲线符合一级反应动力学方程,于上述最佳条件下其表观反应速率常数k达到最大值,为0.389 7 h-1

    Abstract:

    Fe-doped anatase TiO2 (A-TiO2)photocatalyst was prepared through a hydrothermal procedure by using FeCl3·6H2O as the iron source. With bromocresol green taken as degradation target, the bromocresol greens initial concentration, TiO2 dosage, amount of iron-doped were investigated for their effects on kinetic equation of catalytic degradation reaction by visible light of self made catalyst. The results showed that the degradation rate 76. 05% of bromocresol green was the maximum figure under the following optimal conditions: bromocresol greens initial concentration ρ0 10 mg/L(pH=7), catalyst dosage m 0. 6 g/L, amount of iron-doped 4 %(molar fraction), and irradiated by 40 W filament lamp for t=3 h at room temperature. The photocatalytic degradation curve of bromocresol green conformed to the first-order reaction kinetic equation. Under the above optimum conditions, the observed reaction rate constant K achieved the maximum value of 0. 389 7 h-1.

    参考文献
    相似文献
    引证文献
引用本文

张一兵,冯永青,谢丽丽,等. Fe掺杂A-TiO2在溴甲酚绿中的可见光催化活性及动力学[J].水资源保护,2017,33(6):87-91.(ZHANG Yibing, FENG Yongqing, XIE Lili, et al. Visible light catalytic activity and kinetics of Fe-doped A-TiO2 in bromocresol green[J]. Water Resources Protection,2017,33(6):87-91.(in Chinese))

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2016-11-28
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期: 2017-11-24
  • 出版日期: